Category Archives: Science

Einstein 1938: The First Serious Difficulty

Reference: Evolution of Physics

This paper presents Chapter II, section 3 from the book THE EVOLUTION OF PHYSICS by A. EINSTEIN and L. INFELD. The contents are from the original publication of this book by Simon and Schuster, New York (1942).

The paragraphs of the original material (in black) are accompanied by brief comments (in color) based on the present understanding.  Feedback on these comments is appreciated.

The heading below is linked to the original materials.

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The First Serious Difficulty

We are now ready to note the first grave difficulty in the application of our general philosophical point of view. It will be shown later that this difficulty, together with another even more serious, caused a complete breakdown of the belief that all phenomena can be explained mechanically.

The mechanical view is to describe all phenomena by means of attractive and repulsive forces depending only on distance and acting between unchangeable particles. This view has serious flaws.

The tremendous development of electricity as a branch of science and technique began with the discovery of the electric current. Here we find in the history of science one of the very few instances in which accident seemed to play an essential role. The story of the convulsion of a frog’s leg is told in many different ways. Regardless of the truth concerning details, there is no doubt that Galvani’s accidental discovery led Volta at the end of the eighteenth century to the construction of what is known as a voltaic battery. This is no longer of any practical use, but it still furnishes a very simple example of a source of current in school demonstrations and in textbook descriptions.

Galvani’s observation of the convulsion of a frog’s leg led Volta to construct a voltaic battery as a source of electric current. This accidental discovery of the electric current led to the tremendous development of electricity as a branch of science.

The principle of its construction is simple. There are several glass tumblers, each containing water with a little sulphuric acid. In each glass two metal plates, one copper and the other zinc, are immersed in the solution. The copper plate of one glass is connected to the zinc of the next, so that only the zinc plate of the first and the copper plate of the last glass remain unconnected. We can detect a difference in electric potential between the copper in the first glass and the zinc in the last by means of a fairly sensitive electroscope if the number of the “elements”, that is, glasses with plates, constituting the battery, is sufficiently large.

The voltaic battery, constructed with two different metals in a solution of acid, produces enough electric potential difference between those metals to be detected by an electroscope.

It was only for the purpose of obtaining something easily measurable with apparatus already described that we introduced a battery consisting of several elements. For further discussion, a single element will serve just as well. The potential of the copper turns out to be higher than that of the zinc. “Higher” is used here in the sense in which +2 is greater than -2. If one conductor is connected to the free copper plate and another to the zinc, both will become charged, the first positively and the other negatively. Up to this point nothing particularly new or striking has appeared, and we may try to apply our previous ideas about potential differences. We have seen that a potential difference between two conductors can be quickly nullified by connecting them with a wire, so that there is a flow of electric fluid from one conductor to the other. This process was similar to the equalization of temperatures by heat flow. But does this work in the case of a voltaic battery? Volta wrote in his report that the plates behave like conductors:

. . . feebly charged, which act unceasingly or so that their charge after each discharge re-establishes itself; which, in a word, provides an unlimited charge or imposes a perpetual action or impulsion of the electric fluid.

The electric potential difference was expected to discharge when the two metals were connected, but, instead, there was an unceasing flow of charge.

The astonishing result of his experiment is that the potential difference between the copper and zinc plates does not vanish as in the case of two charged conductors connected by a wire. The difference persists, and according to the fluids theory it must cause a constant flow of electric fluid from the higher potential level (copper plate) to the lower (zinc plate). In an attempt to save the fluid theory, we may assume that some constant force acts to regenerate the potential difference and cause a flow of electric fluid. But the whole phenomenon is astonishing from the standpoint of energy. A noticeable quantity of heat is generated in the wire carrying the current, even enough to melt the wire if it is a thin one. Therefore, heat-energy is created in the wire. But the whole voltaic battery forms an isolated system, since no external energy is being supplied. If we want to save the law of conservation of energy we must find where the transformations take place, and at what expense the heat is created. It is not difficult to realize that complicated chemical processes are taking place in the battery, processes in which the immersed copper and zinc, as well as the liquid itself, take active parts. From the standpoint of energy this is the chain of transformations which are taking place: chemical energy energy of the flowing electric fluid, i.e., the current heat. A voltaic battery does not last for ever; the chemical changes associated with the flow of electricity make the battery useless after a time.

From the standpoint of conservation of energy this is the chain of transformations which are taking place: chemical energy → energy of the flowing electric fluid, i.e., the current → heat.

The experiment which actually revealed the great difficulties in applying the mechanical ideas must sound strange to anyone hearing about it for the first time. It was performed by Oersted about a hundred and twenty years ago. He reports:

By these experiments it seems to be shown that the magnetic needle was moved from its position by help of a galvanic apparatus, and that, when the galvanic circuit was closed, but not when open, as certain very celebrated physicists in vain attempted several years ago.

Suppose we have a voltaic battery and a conducting wire. If the wire is connected to the copper plate but not to the zinc, there will exist a potential difference but no current can flow. Let us assume that the wire is bent to form a circle, in the centre of which a magnetic needle is placed, both wire and needle lying in the same plane. Nothing happens so long as the wire does not touch the zinc plate. There are no forces acting, the existing potential difference having no influence whatever on the position of the needle. It seems difficult to understand why the “very celebrated physicists”, as Oersted called them, expected such an influence.

But now let us join the wire to the zinc plate. Immediately a strange thing happens. The magnetic needle turns from its previous position. One of its poles now points to the reader if the page of this book represents the plane of the circle. The effect is that of a force, perpendicular to the plane, acting on the magnetic pole. Faced with the facts of the experiment, we can hardly avoid drawing such a conclusion about the direction of the force acting.

The moment the circular wire is joined to the zinc plate, the magnetic needle turns, as if there is a force acting on the magnetic pole, perpendicular to the plane of the wire.

This experiment is interesting, in the first place, because it shows a relation between two apparently quite different phenomena, magnetism and electric current. There is another aspect even more important. The force between the magnetic pole and the small portions of the wire through which the current flows cannot lie along lines connecting the wire and needle, or the particles of flowing electric fluid and the elementary magnetic dipoles. The force is perpendicular to these lines! For the first time there appears a force quite different from that to which, according to our mechanical point of view, we intended to reduce all actions in the external world. We remember that the forces of gravitation, electrostatics, and magnetism, obeying the laws of Newton and Coulomb, act along the line adjoining the two attracting or repelling bodies.

Here we see a relation between two apparently quite different phenomena, magnetism and electric current. Furthermore, the force is perpendicular to the lines connecting the wire and the needle, unlike the mechanical forces.

This difficulty was stressed even more by an experiment performed with great skill by Rowland nearly sixty years ago. Leaving out technical details, this experiment could be described as follows. Imagine a small charged sphere. Imagine further that this sphere moves very fast in a circle at the centre of which is a magnetic needle. This is, in principle, the same experiment as Oersted’s, the only difference being that instead of an ordinary current we have a mechanically effected motion of the electric charge. Rowland found that the result is indeed similar to that observed when a current flows in a circular wire. The magnet is deflected by a perpendicular force.

Let us now move the charge faster. The force acting on the magnetic pole is, as a result, increased; the deflection from its initial position becomes more distinct. This observation presents another grave complication. Not only does the force fail to lie on the line connecting charge and magnet, but the intensity of the force depends on the velocity of the charge. The whole mechanical point of view was based on the belief that all phenomena can be explained in terms of forces depending only on the distance and not on the velocity. The result of Rowland’s experiment certainly shakes this belief. Yet we may choose to be conservative and seek a solution within the frame of old ideas.

Not only does the force fail to lie on the line connecting charge and magnet, but the intensity of the force depends on the velocity of the charge, and not on the distance as is the case with mechanical forces.

Difficulties of this kind, sudden and unexpected obstacles in the triumphant development of a theory, arise frequently in science. Sometimes a simple generalization of the old ideas seems, at least temporarily, to be a good way out. It would seem sufficient in the present case, for example, to broaden the previous point of view and introduce more general forces between the elementary particles. Very often, however, it is impossible to patch up an old theory, and the difficulties result in its downfall and the rise of a new one. Here it was not only the behaviour of a tiny magnetic needle which broke the apparently well-founded and successful mechanical theories. Another attack, even more vigorous, came from an entirely different angle. But this is another story, and we shall tell it later.

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Final Comment

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Einstein 1938: The Magnetic Fluids

Reference: Evolution of Physics

This paper presents Chapter II, section 2 from the book THE EVOLUTION OF PHYSICS by A. EINSTEIN and L. INFELD. The contents are from the original publication of this book by Simon and Schuster, New York (1942).

The paragraphs of the original material (in black) are accompanied by brief comments (in color) based on the present understanding.  Feedback on these comments is appreciated.

The heading below is linked to the original materials.

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The Magnetic Fluids

We shall proceed here in the same manner as before, starting with very simple facts and then seeking their theoretical explanation.

1. We have two long bar magnets, one suspended freely at its centre, the other held in the hand. The ends of the two magnets are brought together in such a way that a strong attraction is noticed between them. This can always be done. If no attraction results, we must turn the magnet and try the other end. Something will happen if the bars are magnetized at all. The ends of the magnets are called their poles. To continue with the experiment we move the pole of the magnet held in the hand along the other magnet. A decrease in the attraction is noticed and when the pole reaches the middle of the suspended magnet there is no evidence of any force at all. If the pole is moved farther in the same direction a repulsion is observed, attaining its greatest strength at the second pole of the hanging magnet.

2. The above experiment suggests another. Each magnet has two poles. Can we not isolate one of them? The idea is very simple: just break a magnet into two equal parts. We have seen that there is no force between the pole of one magnet and the middle of the other. But the result of actually breaking a magnet is surprising and unexpected. If we repeat the experiment described under 1, with only half a magnet suspended, the results are exactly the same as before! Where there was no trace of magnetic force previously, there is now a strong pole.

How are these facts to be explained? We can attempt to pattern a theory of magnetism after the theory of electric fluids. This is suggested by the fact that here, as in electrostatic phenomena, we have attraction and repulsion. Imagine two spherical conductors possessing equal charges, one positive and the other negative. Here “equal” means having the same absolute value; + 5 and 5, for example, have the same absolute value. Let us assume that these spheres are connected by means of an insulator such as a glass rod. Schematically this arrangement can be represented by an arrow directed from the negatively charged conductor to the positive one. We shall call the whole thing an electric dipole. It is clear that two such dipoles would behave exactly like the bar magnets in experiment 1. If we think of our invention as a model for a real magnet, we may say, assuming the existence of magnetic fluids, that a magnet is nothing but a magnet dipole, having at its ends two fluids of different kinds. This simple theory, imitating the theory of electricity, is adequate for an explanation of the first experiment. There would be attraction at one end, repulsion at the other, and a balancing of equal and opposite forces in the middle. But what of the second experiment? By breaking the glass rod in the case of the electric dipole we get two isolated poles. The same ought to hold good for the iron bar of the magnetic dipole, contrary to the results of the second experiment. Thus this contradiction forces us to introduce a somewhat more subtle theory. Instead of our previous model we may imagine that the magnet consists of very small elementary magnetic dipoles which cannot be broken into separate poles. Order reigns in the magnet as a whole, for all the elementary dipoles are directed in the same way. We see immediately why cutting a magnet causes two new poles to appear on the new ends, and why this more refined theory explains the facts of experiment 1 as well as 2.

Each magnet has two poles. Similar to the electrostatic phenomena, opposite poles attract; and like poles repel each other; but the magnetic poles cannot be isolated. Cutting a magnet causes two new poles to appear on the new ends. We theorize that the magnet consists of very small elementary magnetic dipoles directed in the same way. The elementary magnetic dipoles cannot be broken into separate poles.

For many facts, the simpler theory gives an explanation and the refinement seems unnecessary. Let us take an example: We know that a magnet attracts pieces of iron. Why? In a piece of ordinary iron the two magnetic fluids are mixed, so that no net effect results. Bringing a positive pole near acts as a “command of division” to the fluids, attracting the negative fluid of the iron and repelling the positive. The attraction between iron and magnet follows. If the magnet is removed, the fluids go back to more or less their original state, depending on the extent to which they remember the commanding voice of the external force.

The magnetic dipoles are mixed in the iron, but they manage to order themselves in the presence of a magnet.

Little need be said about the quantitative side of the problem. With two very long magnetized rods we could investigate the attraction (or repulsion) of their poles when brought near one another. The effect of the other ends of the rods is negligible if the rods are long enough. How does the attraction or repulsion depend on the distance between the poles? The answer given by Coulomb’s experiment is that this dependence on distance is the same as in Newton’s law of gravitation and Coulomb’s law of electrostatics.

The dependence on distance in magnetic attraction (or repulsion) is the same as in Newton’s law of gravitation and Coulomb’s law of electrostatics.

We see again in this theory the application of a general point of view: the tendency to describe all phenomena by means of attractive and repulsive forces depending only on distance and acting between unchangeable particles.

All phenomena may be described by means of attractive and repulsive forces depending only on distance.

One well-known fact should be mentioned, for later we shall make use of it. The earth is a great magnetic dipole. There is not the slightest trace of an explanation as to why this is true. The North Pole is approximately the minus (-) and the South Pole the plus (+) magnetic pole of the earth. The names plus and minus are only a matter of convention, but when once fixed, enable us to designate poles in any other case. A magnetic needle supported on a vertical axis obeys the command of the magnetic force of the earth. It directs its (+) pole toward the North Pole, that is, toward the (-) magnetic pole of the earth.

The earth is a great magnetic dipole.

Although we can consistently carry out the mechanical view in the domain of electric and magnetic phenomena introduced here, there is no reason to be particularly proud or pleased about it. Some features of the theory are certainly unsatisfactory if not discouraging. New kinds of substances had to be invented: two electric fluids and the elementary magnetic dipoles. The wealth of substances begins to be overwhelming!

Here we are inventing new substances (heat, electric charges, magnetic dipoles).

The forces are simple. They are expressible in a similar way for gravitational, electric, and magnetic forces. But the price paid for this simplicity is high: the introduction of new weightless substances. These are rather artificial concepts, and quite unrelated to the fundamental substance, mass.

These weightless substances are rather artificial concepts, and quite unrelated to the fundamental substance, mass.

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Final Comment

In this mechanical view, there are new weightless substances (heat, electric charges, magnetic dipoles) that involve forces that seem to behave very similar to the gravitational force. But gravitational force involves mass as substance.

How do they all relate?

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Einstein 1938: The Two Electric Fluids

Reference: Evolution of Physics

This paper presents Chapter II, section 1 from the book THE EVOLUTION OF PHYSICS by A. EINSTEIN and L. INFELD. The contents are from the original publication of this book by Simon and Schuster, New York (1942).

The paragraphs of the original material (in black) are accompanied by brief comments (in color) based on the present understanding.  Feedback on these comments is appreciated.

The heading below is linked to the original materials.

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The Two Electric Fluids

The following pages contain a dull report of some very simple experiments. The account will be boring not only because the description of experiments is uninteresting in comparison with their actual performance, but also because the meaning of the experiments does not become apparent until theory makes it so. Our purpose is to furnish a striking example of the role of theory in physics.

1. A metal bar is supported on a glass base, and each end of the bar is connected by means of a wire to an electroscope. What is an electroscope? It is a simple apparatus consisting essentially of two leaves of gold foil hanging from the end of a short piece of metal. This is enclosed in a glass jar or flask and the metal is in contact only with non-metallic bodies, called insulators. In addition to the electroscope and metal bar we are equipped with a hard rubber rod and a piece of flannel.

The experiment is performed as follows: we look to see whether the leaves hang close together, for this is their normal position. If by chance they do not, a touch of the finger on the metal rod will bring them together. These preliminary steps being taken, the rubber rod is rubbed vigorously with the flannel and brought into contact with the metal. The leaves separate at once! They remain apart even after the rod is removed.

2. We perform another experiment, using the same apparatus as before, again starting with the gold leaves hanging close together. This time we do not bring the rubbed rod into actual contact with the metal, but only near it. Again the leaves separate. But there is a difference! When the rod is taken away without having touched the metal, the leaves immediately fall back to their normal position instead of remaining separated.

3. Let us change the apparatus slightly for a third experiment. Suppose that the metal bar consists of two pieces, joined together. We rub the rubber rod with flannel and again bring it near the metal. The same phenomenon occurs, the leaves separate. But now let us divide the metal rod into its two separate parts and then take away the rubber rod. We notice that in this case the leaves remain apart, instead of falling back to their normal position as in the second experiment.

It is difficult to evince enthusiastic interest in these simple and naive experiments. In the Middle Ages their performer would probably have been condemned; to us they seem both dull and illogical. It would be very difficult to repeat them, after reading the account only once, without becoming confused. Some notion of the theory makes them understandable. We could say more: it is hardly possible to imagine such experiments performed as accidental play, without the pre-existence of more or less definite ideas about their meaning.

We shall now point out the underlying ideas of a very simple and naive theory which explains all the facts described.

There exist two electric fluids, one called positive (+) and the other negative (-). They are somewhat like substance in the sense already explained, in that the amount can be enlarged or diminished, but the total in any isolated system is preserved. There is, however, an essential difference between this case and that of heat, matter or energy. We have two electrical substances. It is impossible here to use the previous analogy of money unless it is somehow generalized. A body is electrically neutral if the positive and negative electric fluids exactly cancel each other. A man has nothing, either because he really has nothing, or because the amount of money put aside in his safe is exactly equal to the sum of his debts. We can compare the debit and credit entries in his ledger to the two kinds of electric fluids.

A property of substance is that its amount can be enlarged or diminished, but the total in any isolated system is preserved. In the case of electricity there exist two electric fluids that neutralize each other.

The next assumption of the theory is that two electric fluids of the same kind repel each other, while two of the opposite kind attract. This can be represented graphically in the following way:

Two electric fluids of the same kind repel each other, while two of the opposite kind attract.

A final theoretical assumption is necessary: There are two kinds of bodies, those in which the fluids can move freely, called conductors, and those in which they cannot, called insulators. As is always true in such cases, this division is not to be taken too seriously. The ideal conductor or insulator is a fiction which can never be realized. Metals, the earth, the human body, are all examples of conductors, although not equally good. Glass, rubber, china, and the like are insulators. Air is only partially an insulator, as everyone who has seen the described experiments knows. It is always a good excuse to ascribe the bad results of electrostatic experiments to the humidity of the air, which increases its conductivity.

There are two kinds of bodies, those in which the fluids can move freely, called conductors, and those in which they cannot, called insulators.

These theoretical assumptions are sufficient to explain the three experiments described. We shall discuss them once more, in the same order as before, but in the light of the theory of electric fluids.

1. The rubber rod, like all other bodies under normal conditions, is electrically neutral. It contains the two fluids, positive and negative, in equal amounts. By rubbing with flannel we separate them. This statement is pure convention, for it is the application of the terminology created by the theory to the description of the process of rubbing. The kind of electricity that the rod has in excess afterwards is called negative, a name which is certainly only a matter of convention. If the experiments had been performed with a glass rod rubbed with cat’s fur we should have had to call the excess positive, to conform with the accepted convention. To proceed with the experiment, we bring electric fluid to the metal conductor by touching it with the rubber. Here it moves freely, spreading over the whole metal including the gold leaves. Since the action of negative on negative is repulsion, the two leaves try to get as far from each other as possible and the result is the observed separation. The metal rests on glass or some other insulator so that the fluid remains on the conductor, as long as the conductivity of the air permits. We understand now why we have to touch the metal before beginning the experiment. In this case the metal, the human body, and the earth form one vast conductor, with the electric fluid so diluted that practically nothing remains on the electroscope.

2. This experiment begins just in the same way as the previous one. But instead of being allowed to touch the metal the rubber is now only brought near it. The two fluids in the conductor, being free to move, are separated, one attracted and the other repelled. They mix again when the rubber rod is removed, as fluids of opposite kinds attract each other.

3. Now we separate the metal into two parts and afterwards remove the rod. In this case the two fluids cannot mix, so that the gold leaves retain an excess of one electric fluid and remain apart.

In the light of this simple theory all the facts mentioned here seem comprehensible. The same theory does more, enabling us to understand not only these, but many other facts in the realm of “electrostatics”. The aim of every theory is to guide us to new facts, suggest new experiments, and lead to the discovery of new phenomena and new laws. An example will make this clear. Imagine a change in the second experiment. Suppose I keep the rubber rod near the metal and at the same time touch the conductor with my finger. What will happen now? Theory answers: the repelled fluid (-) can now make its escape through my body, with the result that only one fluid remains, the positive. Only the leaves of the electroscope near the rubber rod will remain apart. An actual experiment confirms this prediction.

The theory with which we are dealing is certainly naive and inadequate from the point of view of modern physics. Nevertheless it is a good example showing the characteristic features of every physical theory.

The above theory of electricity explains the experimental observations.

There are no eternal theories in science. It always happens that some of the facts predicted by a theory are disproved by experiment. Every theory has its period of gradual development and triumph, after which it may experience a rapid decline. The rise and fall of the substance theory of heat, already discussed here, is one of many possible examples. Others, more profound and important, will be discussed later. Nearly every great advance in science arises from a crisis in the old theory, through an endeavour to find a way out of the difficulties created. We must examine old ideas, old theories, although they belong to the past, for this is the only way to understand the importance of the new ones and the extent of their validity.

Older theories are superseded by later theories based on new observations.

In the first pages of our book we compared the role of an investigator to that of a detective who, after gathering the requisite facts, finds the right solution by pure thinking. In one essential this comparison must be regarded as highly superficial. Both in life and in detective novels the crime is given. The detective must look for letters, fingerprints, bullets, guns, but at least he knows that a murder has been committed. This is not so for a scientist. It should not be difficult to imagine someone who knows absolutely nothing about electricity, since all the ancients lived happily enough without any knowledge of it. Let this man be given metal, gold foil, bottles, hard-rubber rod, flannel, in short, all the material required for performing our three experiments. He may be a very cultured person, but he will probably put wine into the bottles, use the flannel for cleaning, and never once entertain the idea of doing the things we have described. For the detective the crime is given, the problem formulated: who killed Cock Robin? The scientist must, at least in part, commit his own crime, as well as carry out the investigation. Moreover, his task is not to explain just one case, but all phenomena which have happened or may still happen.

Scientific investigations proceed on the basis of pure curiosity.

In the introduction of the concept of fluids we see the influence of those mechanical ideas which attempt to explain everything by substances and simple forces acting between them. To see whether the mechanical point of view can be applied to the description of electrical phenomena, we must consider the following problem. Two small spheres are given, both with an electric charge, that is, both carrying an excess of one electric fluid. We know that the spheres will either attract or repel each other. But does the force depend only on the distance, and if so, how? The simplest guess seems to be that this force depends on the distance in the same way as gravitational force, which diminishes, say, to one-ninth of its former strength if the distance is made three times as great. The experiments performed by Coulomb showed that this law is really valid. A hundred years after Newton discovered the law of gravitation, Coulomb found a similar dependence of electrical force on distance. The two major differences between Newton’s law and Coulomb’s law are: gravitational attraction is always present, while electric forces exist only if the bodies possess electric charges. In the gravitational case there is only attraction, but electric forces may either attract or repel.

There is similarity between the laws that govern gravitational and electrical force. Gravitational attraction is always present, while electric forces exist only if the bodies possess electric charges. In the gravitational case there is only attraction, but electric forces may either attract or repel.

There arises here the same question which we considered in connection with heat. Are the electrical fluids weightless substances or not? In other words, is the weight of a piece of metal the same whether neutral or charged? Our scales show no difference. We conclude that the electric fluids are also members of the family of weightless substances.

The electric fluids are also members of the family of weightless substances.

Further progress in the theory of electricity requires the introduction of two new concepts. Again we shall avoid rigorous definitions, using instead analogies with concepts already familiar. We remember how essential it was for an understanding of the phenomena of heat to distinguish between heat itself and temperature. It is equally important here to distinguish between electric potential and electric charge. The difference between the two concepts is made clear by the analogy:

Two conductors, for example two spheres of different size, may have the same electric charge, that is the same excess of one electric fluid, but the potential will be different in the two cases, being higher for the smaller and lower for the larger sphere. The electric fluid will have greater density and thus be more compressed on the small conductor. Since the repulsive forces must increase with the density, the tendency of the charge to escape will be greater in the case of the smaller sphere than in that of the larger. This tendency of charge to escape from a conductor is a direct measure of its potentials. In order to show clearly the difference between charge and potential we shall formulate a few sentences describing the behaviour of heated bodies, and the corresponding sentences concerning charged conductors.

But this analogy must not be pushed too far. An example shows the differences as well as the similarities. If a hot body is brought into contact with a cold one, the heat flows from the hotter to the colder. On the other hand, suppose that we have two insulated conductors having equal but opposite charges, one positive and the other negative. The two are at different potentials. By convention we regard the potential corresponding to a negative charge as lower than that corresponding to a positive charge. If the two conductors are brought together or connected by a wire, it follows from the theory of electric fluids that they will show no charge and thus no difference of electric potential at all. We must imagine a “flow” of electric charge from one conductor to the other during the short time in which the potential difference is equalized. But how? Does the positive fluid flow to the negative body, or the negative fluid to the positive body?

Hot and cold temperatures can be put on the same scale, but this is not so with positive and negative electricity.

In the material presented here we have no basis for deciding between these two alternatives. We can assume either of the two possibilities, or that the flow is simultaneous in both directions. It is only a matter of adopting a convention, and no significance can be attached to the choice, for we know no method of deciding the question experimentally. Further development leading to a much more profound theory of electricity gave an answer to this problem, which is quite meaningless when formulated in terms of the simple and primitive theory of electric fluids. Here we shall simply adopt the following mode of expression. The electric fluid flows from the conductor having the higher potential to that having the lower. In the case of our two conductors, the electricity thus flows from positive to negative. This expression is only a matter of convention and is at this point quite arbitrary. The whole difficulty indicates that the analogy between heat and electricity is by no means complete.

The positive and negative potentials are arbitrarily assigned under the two fluids theory.

We have seen the possibility of adapting the mechanical view to a description of the elementary facts of electrostatics. The same is possible in the case of magnetic phenomena.

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Final Comment

Postive and negative charges represent two opposite conditions of tension that can exist in matter. When a positive charge arises in one place then an equivalent negative charge must arise at another place. Opposite charges attract each other. Like charges repel each other. When positive and negative charges come together, they neutralize each other. The amount of charge in a system can be enlarged or diminished. The total charge in any isolated system is preserved.

According to Postulate Mechanics, gravity depends on the balance of inertia and motion among a system of bodies. In this theory, the bodies follow their balanced path. Two bodies when pushed closer shall repel each other. Two bodies when pulled apart shall attract each other. There is neutralization in terms of traveling the balanced path.

Thus, there are parallels between electrical and gravitational forces, but their nature is very different.

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Einstein 1938: The Kinetic Theory of Matter

Reference: Evolution of Physics

This paper presents Chapter I, section 10 from the book THE EVOLUTION OF PHYSICS by A. EINSTEIN and L. INFELD. The contents are from the original publication of this book by Simon and Schuster, New York (1942).

The paragraphs of the original material (in black) are accompanied by brief comments (in color) based on the present understanding.  Feedback on these comments is appreciated.

The heading below is linked to the original materials.

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The Kinetic Theory of Matter

Is it possible to explain the phenomena of heat in terms of the motions of particles interacting through simple forces? A closed vessel contains a certain mass of gas air, for example at a certain temperature. By heating we raise the temperature, and thus increase the energy. But how is this heat connected with motion? The possibility of such a connection is suggested both by our tentatively accepted philosophical point of view and by the way in which heat is generated by motion. Heat must be mechanical energy if every problem is a mechanical one. The object of the kinetic theory is to present the concept of matter just in this way. According to this theory a gas is a congregation of an enormous number of particles, or molecules, moving in all directions, colliding with each other and changing in direction of motion with each collision. There must exist an average speed of molecules, just as in a large human community there exists an average age, or an average wealth. There will therefore be an average kinetic energy per particle. More heat in the vessel means a greater average kinetic energy. Thus heat, according to this picture, is not a special form of energy different from the mechanical one but is just the kinetic energy of molecular motion. To any definite temperature there corresponds a definite average kinetic energy per molecule. This is, in fact, not an arbitrary assumption. We are forced to regard the kinetic energy of a molecule as a measure of the temperature of the gas if we wish to form a consistent mechanical picture of matter.

Heat, according to this picture, is not a special form of energy different from the mechanical one but is just the kinetic energy of molecular motion. To any definite temperature there corresponds a definite average kinetic energy per molecule.

This theory is more than a play of the imagination. It can be shown that the kinetic theory of gases is not only in agreement with experiment, but actually leads to a more profound understanding of the facts. This may be illustrated by a few examples.

We have a vessel closed by a piston which can move freely. The vessel contains a certain amount of gas to be kept at a constant temperature. If the piston is initially at rest in some position, it can be moved upward by removing and downward by adding weight. To push the piston down force must be used acting against the inner pressure of the gas. What is the mechanism of this inner pressure according to the kinetic theory? A tremendous number of particles constituting the gas are moving in all directions. They bombard the walls and the piston, bouncing back like balls thrown against a wall. This continual bombardment by a great number of particles keeps the piston at a certain height by opposing the force of gravity acting downward on the piston and the weights. In one direction there is a constant gravitational force, in the other very many irregular blows from the molecules. The net effect on the piston of all these small irregular forces must be equal to that of the force of gravity if there is to be equilibrium.

The continual bombardment by a great number of particles keeps the piston at a certain height by opposing the force of gravity acting downward on the piston and the weights.

Suppose the piston were pushed down so as to compress the gas to a fraction of its former volume, say one-half, its temperature being kept unchanged. What, according to the kinetic theory, can we expect to happen? Will the force due to the bombardment be more or less effective than before? The particles are now packed more closely. Although the average kinetic energy is still the same, the collisions of the particles with the piston will now occur more frequently and thus the total force will be greater. It is clear from this picture presented by the kinetic theory that to keep the piston in this lower position more weight is required. This simple experimental fact is well known, but its prediction follows logically from the kinetic view of matter.

To keep the piston in a lower position more weight is required. This prediction follows logically from the kinetic view of matter.

Consider another experimental arrangement. Take two vessels containing equal volumes of different gases, say hydrogen and nitrogen, both at the same temperature. Assume the two vessels are closed with identical pistons, on which are equal weights. This means, briefly, that both gases have the same volume, temperature, and pressure. Since the temperature is the same, so, according to the theory, is the average kinetic energy per particle. Since the pressures are equal, the two pistons are bombarded with the same total force. On the average every particle carries the same energy and both vessels have the same volume. Therefore, the number of molecules in each must be the same, although the gases are chemically different. This result is very important for the understanding of many chemical phenomena. It means that the number of molecules in a given volume, at a certain temperature and pressure, is something which is characteristic, not of a particular gas, but of all gases. It is most astonishing that the kinetic theory not only predicts the existence of such a universal number, but enables us to determine it. To this point we shall return very soon.

The kinetic theory predicts the number of molecules in a given volume, at a certain temperature and pressure as a characteristic, not of a particular gas, but of all gases.

The kinetic theory of matter explains quantitatively as well as qualitatively the laws of gases as determined by experiment. Furthermore, the theory is not restricted to gases, although its greatest successes have been in this domain.

A gas can be liquefied by means of a decrease of temperature. A fall in the temperature of matter means a decrease in the average kinetic energy of its particles. It is therefore clear that the average kinetic energy of a liquid particle is smaller than that of a corresponding gas particle.

A striking manifestation of the motion of particles in liquids was given for the first time by the so-called Brownian movement, a remarkable phenomenon which would remain quite mysterious and incomprehensible without the kinetic theory of matter. It was first observed by the botanist Brown, and was explained eighty years later, at the beginning of this century. The only apparatus necessary for observing Brownian motion is a microscope, which need not even be a particularly good one.

Brown was working with grains of pollen of certain plants, that is:

particles or granules of unusually large size varying from one four-thousandth to about five-thousandth of an inch in length.

He reports further:

While examining the form of these particles immersed in water, I observed many of them evidently in motion…. These motions were such as to satisfy me, after frequently repeated observation, that they arose neither from current in the fluid nor from its gradual evaporation, but belonged to the particle itself.

What Brown observed was the unceasing agitation of the granules when suspended in water and visible through the microscope. It is an impressive sight!

A similar phenomenon of unceasing agitation is the Brownian movement.

Is the choice of particular plants essential for the phenomenon? Brown answered this question by repeating the experiment with many different plants, and found that all the granules, if sufficiently small, showed such motion when suspended in water. Furthermore, he found the same kind of restless, irregular motion in very small particles of inorganic as well as organic substances. Even with a pulverized fragment of a sphinx he observed the same phenomenon!

How is this motion to be explained? It seems contradictory to all previous experience. Examination of the position of one suspended particle, say every thirty seconds, reveals the fantastic form of its path. The amazing thing is the apparently eternal character of the motion. A swinging pendulum placed in water soon comes to rest if not impelled by some external force. The existence of a never-diminishing motion seems contrary to all experience. This difficulty was splendidly clarified by the kinetic theory of matter.

This movement is splendidly clarified by the kinetic theory of matter.

Looking at water through even our most powerful microscopes we cannot see molecules and their motion as pictured by the kinetic theory of matter. It must be concluded that if the theory of water as a congregation of particles is correct, the size of the particles must be beyond the limit of visibility of the best microscopes. Let us nevertheless stick to the theory and assume that it represents a consistent picture of reality. The Brownian particles visible through a microscope are bombarded by the smaller ones composing the water itself. The Brownian movement exists if the bombarded particles are sufficiently small. It exists because this bombardment is not uniform from all sides and cannot be averaged out, owing to its irregular and haphazard character. The observed motion is thus the result of the unobservable one. The behaviour of the big particles reflects in some way that of the molecules, constituting, so to speak, a magnification so high that it becomes visible through the microscope. The irregular and haphazard character of the path of the Brownian particles reflects a similar irregularity in the path of the smaller particles which constitute matter. We can understand, therefore, that a quantitative study of Brownian movement can give us deeper insight into the kinetic theory of matter. It is apparent that the visible Brownian motion depends on the size of the invisible bombarding molecules. There would be no Brownian motion at all if the bombarding molecules did not possess a certain amount of energy or, in other words, if they did not have mass and velocity. That the study of Brownian motion can lead to a determination of the mass of a molecule is therefore not astonishing.

The irregular and haphazard character of the path of the Brownian particles reflects a similar irregularity in the path of the smaller particles which constitute matter.

Through laborious research, both theoretical and experimental, the quantitative features of the kinetic theory were formed. The clue originating in the phenomenon of Brownian movement was one of those which led to the quantitative data. The same data can be obtained in different ways, starting from quite different clues. The fact that all these methods support the same view is most important, for it demonstrates the internal consistency of the kinetic theory of matter.

Experiments show an internal consistency of the kinetic theory of matter.

Only one of the many quantitative results reached by experiment and theory will be mentioned here. Suppose we have a gram of the lightest of all elements, hydrogen, and ask: how many particles are there in this one gram? The answer will characterize not only hydrogen but also all other gases, for we already know under what conditions two gases have the same number of particles.

The theory enables us to answer this question from certain measurements of the Brownian motion of a suspended particle. The answer is an astonishingly great number: a three followed by twenty-three other digits! The number of molecules in one gram of hydrogen is 303,000,000,000,000,000,000,000.

Imagine the molecules of a gram of hydrogen so increased in size that they are visible through a microscope: say that the diameter becomes one five-thousandth of an inch, such as that of a Brownian particle. Then, to pack them closely, we should have to use a box each side of which is about one-quarter of a mile long!

We can easily calculate the mass of one such hydrogen molecule by dividing 1 by the number quoted above. The answer is a fantastically small number: 0.000 000 000 000 000 000 000 0033 gram, representing the mass of one molecule of hydrogen.

The experiments on Brownian motion are only some of the many independent experiments leading to the determination of this number which plays such an important part in physics.

In the kinetic theory of matter and in all its important achievements we see the realization of the general philosophical programme: to reduce the explanation of all phenomena to the interaction between particles of matter.

Kinetic theory of matter tells us that matter is made up of very small particles called atoms and molecules that are continually moving or vibrating.

WE SUMMARIZE:

In mechanics the future path of a moving body can be predicted and its past disclosed if its present condition and the forces acting upon it are known. Thus, for example, the future paths of all planets can be foreseen. The active forces are Newton’s gravitational forces depending on the distance alone. The great results of classical mechanics suggest that the mechanical view can be consistently applied to all branches of physics, that all phenomena can be explained by the action of forces representing either attraction or repulsion, depending only upon distance and acting between unchangeable particles.

In the kinetic theory of matter we see how this view, arising from mechanical problems, embraces the phenomena of heat and how it leads to a successful picture of the structure of matter.

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Final Comment

The kinetic theory of matter tells us that matter is made up of very small particles called atoms and molecules that are continually moving or vibrating. Heat is just the kinetic energy of molecular motion. To any definite temperature there corresponds a definite average kinetic energy per molecule.

The kinetic theory predicts the number of molecules in a given volume, at a certain temperature and pressure as a characteristic, not of a particular gas, but of all gases. This has been verified experimentally.

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Einstein 1938: The Philosophical Background

Reference: Evolution of Physics

This paper presents Chapter I, section 9 from the book THE EVOLUTION OF PHYSICS by A. EINSTEIN and L. INFELD. The contents are from the original publication of this book by Simon and Schuster, New York (1942).

The paragraphs of the original material (in black) are accompanied by brief comments (in color) based on the present understanding.  Feedback on these comments is appreciated.

The heading below is linked to the original materials.

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The Philosophical Background

The results of scientific research very often force a change in the philosophical view of problems which extend far beyond the restricted domain of science itself. What is the aim of science? What is demanded of a theory which attempts to describe nature? These questions, although exceeding the bounds of physics, are intimately related to it, since science forms the material from which they arise. Philosophical generalizations must be founded on scientific results. Once formed and widely accepted, however, they very often influence the further development of scientific thought by indicating one of the many possible lines of procedure. Successful revolt against the accepted view results in unexpected and completely different developments, becoming a source of new philosophical aspects. These remarks necessarily sound vague and pointless until illustrated by examples quoted from the history of physics.

We shall here try to describe the first philosophical ideas on the aim of science. These ideas greatly influenced the development of physics until nearly a hundred years ago, when their discarding was forced by new evidence, new facts and theories, which in their turn formed a new background for science.

In the whole history of science from Greek philosophy to modern physics there have been constant attempts to reduce the apparent complexity of natural phenomena to some simple fundamental ideas and relations. This is the underlying principle of all natural philosophy. It is expressed even in the work of the Atomists. Twenty-three centuries ago Democritus wrote:

By convention sweet is sweet, by convention bitter is bitter, by convention hot is hot, by convention cold is cold, by convention colour is colour. But in reality there are atoms and the void. That is, the objects of sense are supposed to be real and it is customary to regard them as such, but in truth they are not. Only the atoms and the void are real.

The underlying principle of all natural philosophy is to reduce the apparent complexity of natural phenomena to some simple fundamental ideas and relations.

This idea remains in ancient philosophy nothing more than an ingenious figment of the imagination. Laws of nature relating subsequent events were unknown to the Greeks. Science connecting theory and experiment really began with the work of Galileo. We have followed the initial clues leading to the laws of motion. Throughout two hundred years of scientific research force and matter were the underlying concepts in all endeavours to understand nature. It is impossible to imagine one without the other because matter demonstrates its existence as a source of force by its action on other matter.

Throughout two hundred years of scientific research force and matter were the underlying concepts in all endeavours to understand nature.

Let us consider the simplest example: two particles with forces acting between them. The easiest forces to imagine are those of attraction and repulsion. In both cases the force vectors lie on a line connecting the material points. The demand for simplicity leads to the picture of particles attracting or repelling each other; any other assumption about the direction of the acting forces would give a much more complicated picture. Can we make an equally simple assumption about the length of the force vectors? Even if we want to avoid too special assumptions we can still say one thing: the force between any two given particles depends only on the distance between them, like gravitational forces. This seems simple enough. Much more complicated forces could be imagined, such as those which might depend not only on the distance but also on the velocities of the two particles. With matter and force as our fundamental concepts, we can hardly imagine simpler assumptions than that forces act along the line connecting the particles and depend only on the distance. But is it possible to describe all physical phenomena by forces of this kind alone?

With matter and force as our fundamental concepts, we can hardly imagine simpler assumptions than that forces act along the line connecting the particles and depend only on the distance.

The great achievements of mechanics in all its branches, its striking success in the development of astronomy, the application of its ideas to problems apparently different and non-mechanical in character, all these things contributed to the belief that it is possible to describe all natural phenomena in terms of simple forces between unalterable objects. Throughout the two centuries following Galileo’s time such an endeavour, conscious or unconscious, is apparent in nearly all scientific creation. This was clearly formulated by Helmholtz about the middle of the nineteenth century:

Finally, therefore, we discover the problem of physical material science to be to refer natural phenomena back to unchangeable attractive and repulsive forces whose intensity depends wholly upon distance. The solubility of this problem is the condition of the complete comprehensibility of nature.

Thus, according to Helmholtz, the line of development of science is determined and follows strictly a fixed course:

And its vocation will be ended as soon as the reduction of natural phenomena to simple forces is complete and the proof given that this is the only reduction of which the phenomena are capable.

Throughout the two centuries following Galileo’s time, science has held the belief, consciously or unconsciously, that it is possible to describe all natural phenomena in terms of simple forces between unalterable objects.

This view appears dull and naive to a twentieth-century physicist. It would frighten him to think that the great adventure of research could be so soon finished, and an unexciting if infallible picture of the universe established for all time.

Although these tenets would reduce the description of all events to simple forces, they do leave open the question of just how the forces should depend on distance. It is possible that for different phenomena this dependence is different. The necessity of introducing many different kinds of force for different events is certainly unsatisfactory from a philosophical point of view. Nevertheless this so-called mechanical view, most clearly formulated by Helmholtz, played an important role in its time. The development of the kinetic theory of matter is one of the greatest achievements directly influenced by the mechanical view.

This mechanical view led to the development of the kinetic theory of matter.

Before witnessing its decline, let us provisionally accept the point of view held by the physicists of the past century and see what conclusions we can draw from their picture of the external world.

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Final comment

Force and matter are considered to be the underlying concepts in all endeavours to understand nature. Forces are either attractive or repulsive and they act along the line connecting the particles and depend only on the distance. This mechanical view led to the development of the kinetic theory of matter.

Alternative view in Postulate Mechanics is the balance of inertia and motion among particles.

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