The World of Atom (Part XI)

Reference: A Logical Approach to Theoretical Physics



Chapter 54: Atomic Number – Henry G. J. Mosley (1887 – 1915)
The High-Frequency Spectra of the Elements. The structure and chemical behavior of an atom is determined by the charge on the nucleus rather than its mass. The charge on the nucleus is determined by the number of protons in the nucleus (atomic number).

Chapter 55: Quantum Theory of Radiation and Atomic Processes – Albert Einstein (1879 – 1955)
The Quantum Theory of Radiation. Einstein (1917) gave the nuclear atom a logically satisfying structure by deriving the Planck’s radiation formula from the Bohr Theory and stationary states. Einstein showed that radiation is a fully directed phenomenon because the momentum of a quantum must be taken into account. A remarkable aspect of this derivation is the appearance of the stimulated emission process (verified later by the development of Laser).

Chapter 56: The Compton Effect – Arthur H. Compton (1892 – 1962) 
A Quantum Theory of the Scattering of X-Rays by Light Elements. The X-ray beam, after it is scattered by electrons, suffers a definite reduction in frequency. Compton showed that energy of the photon, as given by its frequency, is reduced by the same amount that the kinetic energy of the recoil electron is increased. Thus, the photon is a momentum carrying corpuscle that can transfer its momentum in a given direction to the atom. The Compton effect also implies that the electron must be treated as a wave and not as a particle.

Chapter 57: Space Quantization – Otto Stern (1888 – 1969) Walter Gerlach (1889 – 1979)
Experimental Proof of Space Quantization in a Magnetic Field. The fine structure of spectral lines was explained by the quantization of the angular momentum, in addition to the quantization of electron orbits within the atom. Furthermore, there is “space quantization,” which is the concept that the component of the angular momentum vector along the z-direction can take only certain values.

Chapter 58: Electron Spin – Samuel A. Goudsmit (1902 – 1978) George E. Uhlenbeck (1900 – 1988)
Spinning Electrons and the Structure of Spectra. Electron was assumed to be like a golf ball and its spin was postulated to provide the fourth quantum number to explain the complexities of the atomic spectra, but electron can equally be a wave, with “electron spin” requiring a different explanation. Therefore, electron spin is essentially a mathematical parameter.

The four quantum numbers in atomic physics are: principal quantum number, azimuthal quantum number, magnetic quantum number, and spin quantum number. Together, they describe the unique quantum state of an electron.

The principal quantum number (n) indirectly describes the size of the electron orbital. It has the greatest effect on the energy of the electron. It was first designed to distinguish between different energy levels in the Bohr model of the atom. It is always assigned an integer value (e.g., n = 1, 2, 3…), but its value may never be 0. An orbital for which n = 2 is larger, for example, than an orbital for which n = 1. Energy must be absorbed in order for an electron to be excited from an orbital near the nucleus (n = 1) to get to an orbital further from the nucleus (n = 2).

The azimuthal quantum number (l) for an atomic orbital determines its orbital angular momentum and describes the shape of the orbital. 

The magnetic quantum number (ml): ml = -l, …, 0, …, +l. Specifies the orientation in space of an orbital of a given energy (n) and shape (l). This number divides the sub-shell into individual orbitals which hold the electrons; there are 2l+1 orbitals in each sub-shell.

The spin quantum number (ms) describes the angular momentum of an electron. An electron spins around an axis and has both angular momentum and orbital angular momentum. Because angular momentum is a vector, the Spin Quantum Number (s) has both a magnitude (1/2) and direction (+ or -).

Chapter 59: The Exclusion Principle – Wolfgang Pauli (1900 – 1958) 
Exclusion Principle and Quantum Mechanics. The four quantum numbers were developed following the Bohr’s model to explain the atomic spectra and to establish consistency among the elements in the Periodic table. The Exclusion Principle has assisted greatly in postulating a structure for the atom. The atomic model is essentially based on a mathematical consistency.

Chapter 60: Secondary Radiation – Chandrasekhara Venkata Raman (1888 – 1970) 
A New Class of Spectra Due to Secondary Radiation. When light hits a molecule or an atom, it is scattered. The scattered light contains frequencies equal to, smaller than, and larger than the frequency of the primary light. That part of the incident frequency is absorbed which corresponds to the natural frequency of the molecule, and the rest is scattered, or the natural frequency is added to the incident frequency of the light that is scattered. This is the Raman Effect.

Chapter 61: Statistical Mechanics – S. N. Bose (1894 – 1974) 
Planck’s Law and Light Quantum Hypothesis. Bose applied quantum principle of discrete energy levels to Statistical mechanics. The quantum definition takes the identity of the particles into account. It leads to a distribution different from the Maxwell-Boltzmann distribution, and hence to a different equation of state for a perfect gas. Boyle’s law does not hold for such a gas and the departure from Boyle’s law becomes greater and greater as the temperature decreases.


The mathematical consistency provides insight into the structure of atoms that cannot be perceived otherwise.


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