Eddington 1927: A New Epistemology

quantum

Reference: The Nature of the Physical World

This paper presents Chapter X (section 6) from the book THE NATURE OF THE PHYSICAL WORLD by A. S. EDDINGTON. The contents of this book are based on the lectures that Eddington delivered at the University of Edinburgh in January to March 1927.

The paragraphs of original material are accompanied by brief comments in color, based on the present understanding.  Feedback on these comments is appreciated.

The heading below links to the original materials.

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A New Epistemology

The principle of indeterminacy is epistemological. It reminds us once again that the world of physics is a world contemplated from within surveyed by appliances which are part of it and subject to its laws. What the world might be deemed like if probed in some supernatural manner by appliances not furnished by itself we do not profess to know.

The mystery of indeterminacy resovles with the fifth dimension of quantization.

There is a doctrine well known to philosophers that the moon ceases to exist when no one is looking at it. I will not discuss the doctrine since I have not the least idea what is the meaning of the word existence when used in this connection. At any rate the science of astronomy has not been based on this spasmodic kind of moon. In the scientific world (which has to fulfil functions less vague than merely existing) there is a moon which appeared on the scene before the astronomer; it reflects sunlight when no one sees it; it has mass when no one is measuring the mass; it is distant 240,000 miles from the earth when no one is surveying the distance; and it will eclipse the sun in 1999 even if the human race has succeeding in killing itself off before that date. The moon—the scientific moon—has to play the part of a continuous causal element in a world conceived to be all causally interlocked.

What should we regard as a complete description of this scientific world? We must not introduce anything like velocity through aether, which is meaningless since it is not assigned any causal connection with our experience. On the other hand we cannot limit the description to the immediate data of our own spasmodic observations. The description should include nothing that is unobservable but a great deal that is actually unobserved. Virtually we postulate an infinite army of watchers and measurers. From moment to moment they survey everything that can be surveyed and measure everything that can be measured by methods which we ourselves might conceivably employ. Everything they measure goes down as part of the complete description of the scientific world. We can, of course, introduce derivative descriptions, words expressing mathematical combinations of the immediate measures which may give greater point to the description—so that we may not miss seeing the wood for the trees.

The scientific world is the objective world. It depends on consistency, harmony and continuity of all observations. It exists even when we are not observing it.

By employing the known physical laws expressing the uniformities of Nature we can to a large extent dispense with this army of watchers. We can afford to let the moon out of sight for an hour or two and deduce where it has been in the meantime. But when I assert that the moon (which I last saw in the west an hour ago) is now setting, I assert this not as my deduction but as a true fact of the scientific world. I am still postulating the imaginary watcher; I do not consult him, but I retain him to corroborate my statement if it is challenged. Similarly, when we say that the distance of Sirius is 50 billion miles we are not giving a merely conventional interpretation to its measured parallax; we intend to give it the same status in knowledge as if someone had actually gone through the operation of laying measuring rods end to end and counted how many were needed to reach to Sirius; and we should listen patiently to anyone who produced reasons for thinking that our deductions did not correspond to the “real facts”, i.e. the facts as known to our army of measurers. If we happen to make a deduction which could not conceivably be corroborated or disproved by these diligent measurers, there is no criterion of its truth or falsehood and it is thereby a meaningless deduction.

This theory of knowledge is primarily intended to apply to our macroscopic or large-scale survey of the physical world, but it has usually been taken for granted that it is equally applicable to a microscopic study. We have at last realised the disconcerting fact that though it applies to the moon it does not apply to the electron.

We derive physical laws from consistency, harmony and continuity of observations, and use them to predict new observations. So far our observations have been limited to the macroscopic world. We are now beginning to observe the microscopic world. This may lead to new physical laws.

It does not hurt the moon to look at it. There is no inconsistency in supposing it to have been under the surveillance of relays of watchers whilst we were asleep. But it is otherwise with an electron. At certain times, viz. when it is interacting with a quantum, it might be detected by one of our watchers; but between whiles it virtually disappears from the physical world, having no interaction with it. We might arm our observers with flash-lamps to keep a more continuous watch on its doings; but the trouble is that under the flashlight it will not go on doing what it was doing in the dark. There is a fundamental inconsistency in conceiving the microscopic structure of the physical world to be under continuous survey because the surveillance would itself wreck the whole machine.

We cannot use light to directly observe the non-material sub-atomic world, because light itself needs to be observed.

I expect that at first this will sound to you like a merely dialectical difficulty. But there is much more in it than that. The deliberate frustration of our efforts to bring knowledge of the microscopic world into orderly plan, is a strong hint to alter the plan.

It means that we have been aiming at a false ideal of a complete description of the world. There has not yet been time to make serious search for a new epistemology adapted to these conditions. It has become doubtful whether it will ever be possible to construct a physical world solely out of the knowable—the guiding principle in our macroscopic theories. If it is possible, it involves a great upheaval of the present foundations. It seems more likely that we must be content to admit a mixture of the knowable and unknowable. This means a denial of determinism, because the data required for a prediction of the future will include the unknowable elements of the past. I think it was Heisenberg who said, “The question whether from a complete knowledge of the past we can predict the future, does not arise because a complete knowledge of the past involves a self-contradiction.”

It is only through a quantum action that the outside world can interact with ourselves and knowledge of it can reach our minds. A quantum action may be the means of revealing to us some fact about Nature, but simultaneously a fresh unknown is implanted in the womb of Time. An addition to knowledge is won at the expense of an addition to ignorance. It is hard to empty the well of Truth with a leaky bucket.

A complete description of the world is not a false ideal. The physical senses need to be supported by the mental sense of consistency, harmony and continuity to achieve that ideal.

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Eddington 1927: Principle of Indeterminacy

1901_Heisenberg

Reference: The Nature of the Physical World

This paper presents Chapter X (section 5) from the book THE NATURE OF THE PHYSICAL WORLD by A. S. EDDINGTON. The contents of this book are based on the lectures that Eddington delivered at the University of Edinburgh in January to March 1927.

The paragraphs of original material are accompanied by brief comments in color, based on the present understanding.  Feedback on these comments is appreciated.

The heading below links to the original materials.

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Principle of Indeterminacy

My apprehension lest a fourth version of the new quantum theory should appear before the lectures were delivered was not fulfilled; but a few months later the theory definitely entered on a new phase. It was Heisenberg again who set in motion the new development in the summer of 1927, and the consequences were further elucidated by Bohr. The outcome of it is a fundamental general principle which seems to rank in importance with the principle of relativity. I shall here call it the “principle of indeterminacy”.

The gist of it can be stated as follows : a particle may have position or it may have velocity but it cannot in any exact sense have both.

Both the principles of relativity and indeterminacy come about because of quantization as discussed earlier. Material-substance is highly quantized. The field-substance in “empty” space and within the atom is quantized to a much lesser degree. As quantization becomes less, the substance, space and time become less substantial. The space and time expand and become more diffused.

If we are content with a certain margin of inaccuracy and if we are content with statements that claim no certainty but only high probability, then it is possible to ascribe both position and velocity to a particle. But if we strive after a more accurate specification of position a very remarkable thing happens; the greater accuracy can be attained, but it is compensated by a greater inaccuracy in the specification of the velocity. Similarly if the specification of the velocity is made more accurate the position becomes less determinate.

Science addresses this diffusion of space by means of probability of location.

Suppose for example that we wish to know the position and velocity of an electron at a given moment. Theoretically it would be possible to fix the position with a probable error of about 1/1000 of a millimetre and the velocity with a probable error of 1 kilometre per second. But an error of 1/1000 of a millimetre is large compared with that of some of our space measurements; is there no conceivable way of fixing the position to 1/10,000 of a millimetre? Certainly; but in that case it will only be possible to fix the velocity with an error of 10 kilometres per second.

The error comes about because material units of highly quantized compact space are being used to express measurement.

The conditions of our exploration of the secrets of Nature are such that the more we bring to light the secret of position the more the secret of velocity is hidden. They are like the old man and woman in the weather-glass; as one comes out of one door, the other retires behind the other door. When we encounter unexpected obstacles in finding out something which we wish to know, there are two possible courses to take. It may be that the right course is to treat the obstacle as a spur to further efforts; but there is a second possibility—that we have been trying to find something which does not exist. You will remember that that was how the relativity theory accounted for the apparent concealment of our velocity through the aether.

The hidden influence is that of quantization.

When the concealment is found to be perfectly systematic, then we must banish the corresponding entity from the physical world. There is really no option. The link with our consciousness is completely broken. When we cannot point to any causal effect on anything that comes into our experience, the entity merely becomes part of the unknown—undifferentiated from the rest of the vast unknown. From time to time physical discoveries are made; and new entities, coming out of the unknown, become connected to our experience and are duly named. But to leave a lot of unattached labels floating in the as yet undifferentiated unknown in the hope that they may come in useful later on, is no particular sign of prescience and is not helpful to science. From this point of view we assert that the description of the position and velocity of an electron beyond a limited number of places of decimals is an attempt to describe something that does not exist; although curiously enough the description of position or of velocity if it had stood alone might have been allowable.

The “electron” is used to describe the lesser quantized substance within the atom. The space and time within the atom is diffused compared to the material space and time. Both position and velocity within the atom cannot be measured precisely using material units.

Ever since Einstein’s theory showed the importance of securing that the physical quantities which we talk about are actually connected to our experience, we have been on our guard to some extent against meaningless terms. Thus distance is defined by certain operations of measurement and not with reference to nonsensical conceptions such as the “amount of emptiness” between two points. The minute distances referred to in atomic physics naturally aroused some suspicion, since it is not always easy to say how the postulated measurements could be imagined to be carried out. I would not like to assert that this point has been cleared up; but at any rate it did not seem possible to make a clean sweep of all minute distances, because cases could be cited in which there seemed no natural limit to the accuracy of determination of position. Similarly there are ways of determining momentum apparently unlimited in accuracy. What escaped notice was that the two measurements interfere with one another in a systematic way, so that the combination of position with momentum, legitimate on the large scale, becomes indefinable on the small scale. The principle of indeterminacy is scientifically stated as follows: if q is a co-ordinate and p the corresponding momentum, the necessary uncertainty of our knowledge of q multiplied by the uncertainty of p is of the order of magnitude of the quantum constant h.

A general kind of reason for this can be seen without much difficulty. Suppose it is a question of knowing the position and momentum of an electron. So long as the electron is not interacting with the rest of the universe we cannot be aware of it. We must take our chance of obtaining knowledge of it at moments when it is interacting with something and thereby producing effects that can be observed. But in any such interaction a complete quantum is involved; and the passage of this quantum, altering to an important extent the conditions at the moment of our observation, makes the information out of date even as we obtain it.

Einstein’s theory is interpreted subjectively in terms of the experience of moving observer. This is unscientific and leads to errors. The same theory can be interpreted objectively in terms of quantization (substantialness of substance). This is the basis of Disturbance theory.

The quantum constant ‘h’ is the limiting energy per cycle for material substance. This is the accuracy we measure by. Material position is accurate within the material cycle of infinitesimal wavelength. The quantum of energy for an “electron” is larger and more spread out because wavelength increases at lower quantization. This leads to lesser accuracy in measurements.

Suppose that (ideally) an electron is observed under a powerful microscope in order to determine its position with great accuracy. For it to be seen at all it must be illuminated and scatter light to reach the eye. The least it can scatter is one quantum. In scattering this it receives from the light a kick of unpredictable amount; we can only state the respective probabilities of kicks of different amounts. Thus the condition of our ascertaining the position is that we disturb the electron in an incalculable way which will prevent our subsequently ascertaining how much momentum it had. However, we shall be able to ascertain the momentum with an uncertainty represented by the kick, and if the probable kick is small the probable error will be small. To keep the kick small we must use a quantum of small energy, that is to say, light of long wave-length. But to use long wave-length reduces the accuracy of our microscope. The longer the waves, the larger the diffraction images. And it must be remembered that it takes a great many quanta to outline the diffraction image; our one scattered quantum can only stimulate one atom in the retina of the eye, at some haphazard point within the theoretical diffraction image. Thus there will be an uncertainty in our determination of position of the electron proportional to the size of the diffraction image. We are in a dilemma. We can improve the determination of the position with the microscope by using light of shorter wave-length, but that gives the electron a greater kick and spoils the subsequent determination of momentum.

A picturesque illustration of the same dilemma is afforded if we imagine ourselves trying to see one of the electrons in an atom. For such finicking work it is no use employing ordinary light to see with; it is far too gross, its wave-length being greater than the whole atom. We must use fine-grained illumination and train our eyes to see with radiation of short wave-length— with X-rays in fact. It is well to remember that X-rays have a rather disastrous effect on atoms, so we had better use them sparingly. The least amount we can use is one quantum. Now, if we are ready, will you watch, whilst I flash one quantum of X-rays on to the atom? I may not hit the electron the first time; in that case, of course, you will not see it. Try again; this time my quantum has hit the electron. Look sharp, and notice where it is. Isn’t it there? Bother! I must have blown the electron out of the atom.

This is not a casual difficulty; it is a cunningly arranged plot—a plot to prevent you from seeing something that does not exist, viz. the locality of the electron within the atom. If I use longer waves which do no harm, they will not define the electron sharply enough for you to see where it is. In shortening the wavelength, just as the light becomes fine enough its quantum becomes too rough and knocks the electron out of the atom.

We cannot do direct experimentation, as proposed above, to see reactions within the atom.

Other examples of the reciprocal uncertainty have been given, and there seems to be no doubt that it is entirely general. The suggestion is that an association of exact position with exact momentum can never be discovered by us because there is no such thing in Nature. This is not inconceivable. Schrodinger’s model of the particle as a wave-group gives a good illustration of how it can happen. We have seen (p. 217) that as the position of a wave-group becomes more defined the energy (frequency) becomes more indeterminate, and vice versa. I think that that is the essential value of Schrodinger’s theory; it refrains from attributing to a particle a kind of determinacy which does not correspond to anything in Nature. But I would not regard the principle of indeterminacy as a result to be deduced from Schrodinger’s theory; it is the other way about. The principle of indeterminacy, like the principle of relativity, represents the abandonment of a mistaken assumption which we never had sufficient reason for making. Just as we were misled into untenable ideas of the aether through trusting to an analogy with the material ocean, so we have been misled into untenable ideas of the attributes of the microscopic elements of world-structure through trusting to analogy with gross particles.

The missing concept here is quantization.

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Eddington 1927: Outline of Schrodinger’s Theory

Schrodinger

Reference: The Nature of the Physical World

This paper presents Chapter X (section 4) from the book THE NATURE OF THE PHYSICAL WORLD by A. S. EDDINGTON. The contents of this book are based on the lectures that Eddington delivered at the University of Edinburgh in January to March 1927.

The paragraphs of original material are accompanied by brief comments in color, based on the present understanding.  Feedback on these comments is appreciated.

The heading below links to the original materials.

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Outline of Schrodinger’s Theory

Imagine a sub-aether whose surface is covered with ripples. The oscillations of the ripples are a million times faster than those of visible light—too fast to come within the scope of our gross experience. Individual ripples are beyond our ken; what we can appreciate is a combined effect—when by convergence and coalescence the waves conspire to create a disturbed area of extent large compared with individual ripples but small from our own Brobdingnagian point of view. Such a disturbed area is recognised as a material particle; in particular it can be an electron.

The Disturbance theory starts with the concept of NO SUBSTANCE, which we may refer to as “emptiness”.  This emptiness differs from void in that it neither consists of space nor time because space and time are characteristics of the substance.

In that emptiness the SUBSTANCE appears as a continuum of complex cyclic motion. This is a field of disturbance that has no limit as to its frequency and complexity. We may identify it as field-substance. This is the substance of electromagnetic radiation. The variation of its frequency and complexity produces the electromagnetic spectrum.

As the field-substance increases in frequency and complexity, it becomes more substantial and discrete, though it maintains continuity at the fundamental level.  This inherent property of field-substance is called QUANTIZATION.

This quantization occurs in the atom from periphery to the center. It ends up as the nucleus at the center of the atom. Thus the limiting effect of quantization is to condense the field-substance into material substance.

There is no sub-aether as postulated in Schrodinger’s Theory. There is only field-substance that quantizes into material substance.

The sub-aether is a dispersive medium, that is to say the ripples do not all travel with the same velocity; like water-ripples their speed depends on their wave-length or period. Those of shorter period travel faster. Moreover the speed may be modified by local conditions. This modification is the counterpart in Schrodinger’s theory of a field of force in classical physics. It will readily be understood that if we are to reduce all phenomena to a propagation of waves, then the influence of a body on phenomena in its neighbourhood (commonly described as the field of force caused by its presence) must consist in a modification of the propagation of waves in the region surrounding it.

The greater is the quantization the slower is the speed. The quantization increases with increasing frequency and shortening wavelength and period. Therefore, ripples of shorter period travel slower and not faster. Modification of speed implies change in quantization of substance.

We have to connect these phenomena in the sub-aether with phenomena in the plane of our gross experience. As already stated, a local stormy region is detected by us as a particle; to this we now add that the frequency (number of oscillations per second) of the waves constituting the disturbance is recognised by us as the energy of the particle. We shall presently try to explain how the period manages to manifest itself to us in this curiously camouflaged way; but however it comes about, the recognition of a frequency in the sub-aether as an energy in gross experience gives at once the constant relation between period and energy which we have called the h rule.

Field-substance of higher quantization takes the appearance of field-particles. Each field-particle is formed out of a single cycle of that quantization level. Space and time condenses with increasing quantization and these cycles become shorter in wavelength and period. At the level of material-substance these cycles achieve the limiting condition of infinitesimal size.  The energy per cycle at this limiting condition is the Planck constant ‘h’. The h-rule says that the energy per cycle at lower quantization levels is a multiple of h.

Generally the oscillations in the sub-aether are too rapid for us to detect directly; their frequency reaches the plane of ordinary experience by affecting the speed of propagation, because the speed depends (as already stated) on the wave-length or frequency. Calling the frequency v, the equation expressing the law of propagation of the ripples will contain a term in v. There will be another term expressing the modification caused by the “field of force” emanating from the bodies present in the neighbourhood. This can be treated as a kind of spurious v, since it emerges into our gross experience by the same method that v does. If v produces those phenomena which make us recognise it as energy, the spurious v will produce similar phenomena corresponding to a spurious kind of energy. Clearly the latter will be what we call potential energy, since it originates from influences attributable to the presence of surrounding objects.

The speed of propagation depends on the quantization of the field-substance. We come to know of this quantization from the atomic spectra. The quantization is related to the frequency of light absorbed or emitted. The equation expressing the law of propagation of the ripples shall contain a term in frequency. There will be another term expressing the gradient of quantization.

Assuming that we know both the real v and the spurious or potential v for our ripples, the equation of wave-propagation is settled, and we can proceed to solve any problem concerning wave-propagation. In particular we can solve the problem as to how the stormy areas move about. This gives a remarkable result which provides the first check on our theory. The stormy areas (if small enough) move under precisely the same laws that govern the motions of particles in classical mechanics. The equations for the motion of a wave-group with given frequency and potential frequency are the same as the classical equations of motion of a particle with the corresponding energy and potential energy.

As quantization increases the equations of wave-propagation start to approximate the classical equations of motion of a particle.

It has to be noticed that the velocity of a stormy area or group of waves is not the same as the velocity of an individual wave. This is well known in the study of water-waves as the distinction between group-velocity and wave-velocity. It is the group-velocity that is observed by us as the motion of the material particle.

The motion of a particle is similar to the motion of a wave-group having a group velocity.

We should have gained very little if our theory did no more than re-establish the results of classical mechanics on this rather fantastic basis. Its distinctive merits begin to be apparent when we deal with phenomena not covered by classical mechanics. We have considered a stormy area of so small extent that its position is as definite as that of a classical particle, but we may also consider an area of wider extent. No precise delimitation can be drawn between a large area and a small area, so that we shall continue to associate the idea of a particle with it; but whereas a small concentrated storm fixes the position of the particle closely, a more extended storm leaves it very vague. If we try to interpret an extended wave-group in classical language we say that it is a particle which is not at any definite point of space, but is loosely associated with a wide region.

Schrodinger’s stormy area of small extent is a particle of high quantization. A more extended storm shall represent a “particle” of low quantization. Here we have quantization of space itself. Space becomes more concentrated at higher quantization.

Perhaps you may think that an extended stormy area ought to represent diffused matter in contrast to a concentrated particle. That is not Schrodinger’s theory. The spreading is not a spreading of density; it is an indeterminacy of position, or a wider distribution of the probability that the particle lies within particular limits of position. Thus if we come across Schrodinger waves uniformly filling a vessel, the interpretation is not that the vessel is filled with matter of uniform density, but that it contains one particle which is equally likely to be anywhere.

Here we have the very unit of space expanding with lower quantization. This is captured by Schrodinger’s equation.

The first great success of this theory was in representing the emission of light from a hydrogen atom— a problem far outside the scope of classical theory. The hydrogen atom consists of a proton and electron which must be translated into their counterparts in the sub-aether. We are not interested in what the proton is doing, so we do not trouble about its representation by waves; what we want from it is its field of force, that is to say, the spurious v which it provides in the equation of wave-propagation for the electron. The waves travelling in accordance with this equation constitute Schrodinger’s equivalent for the electron; and any solution of the equation will correspond to some possible state of the hydrogen atom. Now it turns out that (paying attention to the obvious physical limitation that the waves must not anywhere be of infinite amplitude) solutions of this wave-equation only exist for waves with particular frequencies. Thus in a hydrogen atom the sub-aethereal waves are limited to a particular discrete series of frequencies. Remembering that a frequency in the sub-aether means an energy in gross experience, the atom will accordingly have a discrete series of possible energies. It is found that this series of energies is precisely the same as that assigned by Bohr from his rules of quantization (p. 191). It is a considerable advance to have determined these energies by a wave-theory instead of by an inexplicable mathematical rule. Further, when applied to more complex atoms Schrodinger’s theory succeeds on those points where the Bohr model breaks down; it always gives the right number of energies or “orbits” to provide one orbit jump for each observed spectral line.

The Disturbance theory views the hydrogen atom as a single entity. The “proton” as the nucleus serves to anchor the atom and it provides a boundary condition of infinite frequency or quantization. The “electron” then constitutes a series of quantization levels that are decreasing away from the nucleus. There is a high gradient of quantization between the electronic region and the nucleus. Schrodinger’s equation may be modified for Disturbance theory.

It is, however, an advantage not to pass from wave-frequency to classical energy at this stage, but to follow the course of events in the sub-aether a little farther. It would be difficult to think of the electron as having two energies (i.e. being in two Bohr orbits) simultaneously; but there is nothing to prevent waves of two different frequencies being simultaneously present in the sub-aether. Thus the wave-theory allows us easily to picture a condition which the classical theory could only describe in paradoxical terms. Suppose that two sets of waves are present. If the difference of frequency is not very great the two systems of waves will produce “beats”. If two broadcasting stations are transmitting on wave-lengths near together we hear a musical note or shriek resulting from the beats of the two carrier waves; the individual oscillations are too rapid to affect the ear, but they combine to give beats which are slow enough to affect the ear. In the same way the individual wave-systems in the sub-aether are composed of oscillations too rapid to affect our gross senses ; but their beats are sometimes slow enough to come within the octave covered by the eye. These beats are the source of the light coming from the hydrogen atom, and mathematical calculation shows that their frequencies are precisely those of the observed light from hydrogen. Heterodyning of the radio carrier waves produces sound; heterodyning of the sub-aethereal waves produces light. Not only does this theory give the periods of the different lines in the spectra, but it also predicts their intensities —a problem which the older quantum theory had no means of tackling. It should, however, be understood that the beats are not themselves to be identified with light-waves; they are in the sub-aether, whereas light-waves are in the aether. They provide the oscillating source which in some way not yet traced sends out light-waves of its own period.

Schrodinger’s sub-aether is the gamma range of electromagnetic spectrum, which determines the energy of the quantization level itself. The difference between two adjacent quantization levels is related to the frequency of light absorbed or emitted.

What precisely is the entity which we suppose to be oscillating when we speak of the waves in the sub-aether? It is denoted by ψ, and properly speaking we should regard it as an elementary indefinable of the wave-theory. But can we give it a classical interpretation of any kind? It seems possible to interpret it as a probability. The probability of the particle or electron being within a given region is proportional to the amount of ψ in that region. So that if ψ is mainly concentrated in one small stormy area, it is practically certain that the electron is there; we are then able to localise it definitely and conceive of it as a classical particle. But the ip-waves of the hydrogen atom are spread about all over the atom; and there is no definite localisation of the electron, though some places are more probable than others.*

* The probability is often stated to be proportional to ψ2, instead of ψ, as assumed above. The whole interpretation is very obscure, but it seems to depend on whether you are considering the probability after you know what has happened or the probability for the purposes of prediction. The ψ2 is obtained by introducing two symmetrical systems of ψ-waves travelling in opposite directions in time; one of these must presumably correspond to probable inference from what is known (or is stated) to have been the condition at a later time. Probability necessarily means “probability in the light of certain given information”, so that the probability cannot possibly be represented by the same function in different classes of problems with different initial data.

The significance of the wave-function ψ in Schrodinger’s equation seems to be the quantization value of the substance.

Attention must be called to one highly important consequence of this theory. A small enough stormy area corresponds very nearly to a particle moving about under the classical laws of motion; it would seem therefore that a particle definitely localised as a moving point is strictly the limit when the stormy area is reduced to a point. But curiously enough by continually reducing the area of the storm we never quite reach the ideal classical particle; we approach it and then recede from it again. We have seen that the wave-group moves like a particle (localised somewhere within the area of the storm) having an energy corresponding to the frequency of the waves; therefore to imitate a particle exactly, not only must the area be reduced to a point but the group must consist of waves of only one frequency. The two conditions are irreconcilable. With one frequency we can only have an infinite succession of waves not terminated by any boundary. A boundary to the group is provided by interference of waves of slightly different length, so that while reinforcing one another at the centre they cancel one another at the boundary. Roughly speaking, if the group has a diameter of 1000 wavelengths there must be a range of wave-length of o-i per cent., so that 1000 of the longest waves and 1001 of the shortest occupy the same distance. If we take a more concentrated stormy area of diameter 10 wave- lengths the range is increased to 10 per cent.; 10 of the longest and 1 1 of the shortest waves must extend the same distance. In seeking to make the position of the particle more definite by reducing the area we make its energy more vague by dispersing the frequencies of the waves. So our particle can never have simultaneously a perfectly definite position and a perfectly definite energy; it always has a vagueness of one kind or the other unbefitting a classical particle. Hence in delicate experiments we must not under any circumstances expect to find particles behaving exactly as a classical particle was supposed to do—a conclusion which seems to be in accordance with the modern experiments on diffraction of electrons already mentioned.

A classical particle is assumed to be 100% discrete. Since the substance fundamentally forms a continuum, there is no 100% discreteness. Therefore, no field-particle is 100% discrete, even when discreteness increases with quantization.

We remarked that Schrodinger’s picture of the hydrogen atom enabled it to possess something that would be impossible on Bohr’s theory, viz. two energies at once. For a particle or electron this is not merely permissive, but compulsory—otherwise we can put no limits to the region where it may be. You are not asked to imagine the state of a particle with several energies; what is meant is that our current picture of an electron as a particle with single energy has broken down, and we must dive below into the sub-aether if we wish to follow the course of events. The picture of a particle may, however, be retained when we are not seeking high accuracy; if we do not need to know the energy more closely than 1 per cent., a series of energies ranging over 1 per cent, can be treated as one definite energy.

There are no electrons within the atom but quantization levels made up of field-particles, which are not completely discrete.

Hitherto I have only considered the waves corresponding to one electron; now suppose that we have a problem involving two electrons. How shall they be represented? “Surely, that is simple enough! We have only to take two stormy areas instead of one.” I am afraid not. Two stormy areas would correspond to a single electron uncertain as to which area it was located in. So long as there is the faintest probability of the first electron being in any region, we cannot make the Schrodinger waves there represent a probability belonging to a second electron. Each electron wants the whole of three-dimensional space for its waves; so Schrodinger generously allows three dimensions for each of them. For two electrons he requires a six-dimensional sub-aether. He then successfully applies his method on the same lines as before. I think you will see now that Schrodinger has given us what seemed to be a comprehensible physical picture only to snatch it away again. His sub-aether does not exist in physical space; it is in a “configuration space” imagined by the mathematician for the purpose of solving his problems, and imagined afresh with different numbers of dimensions according to the problem proposed. It was only an accident that in the earliest problems considered the configuration space had a close correspondence with physical space, suggesting some degree of objective reality of the waves. Schrodinger’s wave-mechanics is not a physical theory but a dodge—and a very good dodge too.

The Schrodinger’s equation may make more sense if we replace the idea of sub-aether by the gamma region of the electromagnetic spectrum, and replace the idea of electron by quantization levels made up of field-particles.

The fact is that the almost universal applicability of this wave-mechanics spoils all chance of our taking it seriously as a physical theory. A delightful illustration of this occurs incidentally in the work of Dirac. In one of the problems, which he solves by Schrodinger waves, the frequency of the waves represents the number of systems of a given kind. The wave-equation is formulated and solved, and (just as in the problem of the hydrogen atom) it is found that solutions only exist for a series of special values of the frequency. Consequently the number of systems of the kind considered must have one of a discrete series of values. In Dirac’s problem the series turns out to be the series of integers. Accordingly we infer that the number of systems must be either 1, 2, 3, 4, …, but can never be 2¾ r example. It is satisfactory that the theory should give a result so well in accordance with our experience! But we are not likely to be persuaded that the true explanation of why we count in integers is afforded by a system of waves.

Hopefully, the Disturbance theory may be able to provide the true explanation.

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Eddington 1927: Development of the New Quantum Theory

quantization

Reference: The Nature of the Physical World

This paper presents Chapter X (section 3) from the book THE NATURE OF THE PHYSICAL WORLD by A. S. EDDINGTON. The contents of this book are based on the lectures that Eddington delivered at the University of Edinburgh in January to March 1927.

The paragraphs of original material are accompanied by brief comments in color, based on the present understanding.  Feedback on these comments is appreciated.

The heading below links to the original materials.

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Development of the New Quantum Theory

The “New Quantum Theory” originated in a remarkable paper by Heisenberg in the autumn of 1925. I am writing the first draft of this lecture just twelve months after the appearance of the paper. That does not give long for development; nevertheless the theory has already gone through three distinct phases associated with the names of Born and Jordan, Dirac, Schrodinger. My chief anxiety at the moment is lest another phase of reinterpretation should be reached before the lecture can be delivered. In an ordinary way we should describe the three phases as three distinct theories. The pioneer work of Heisenberg governs the whole, but the three theories show wide differences of thought. The first entered on ‘the new road in a rather matter-of-fact way; the second was highly transcendental, almost mystical; the third seemed at first to contain a reaction towards classical ideas, but that was probably a false impression. You will realise the anarchy of this branch of physics when three successive pretenders seize the throne in twelve months; but you will not realise the steady progress made in that time unless you turn to the mathematics of the subject. As regards philosophical ideas the three theories are poles apart; as regards mathematical content they are one and the same. Unfortunately the mathematical content is just what I am forbidden to treat of in these lectures.

Heisenberg’s paper was about the Uncertainty Principle where two related quantities could not be determined accurately even on a theoretical basis. This uncertainty was entering the picture because space and time were being treated as absolute, and the variability in the “substantialness of substance” was not fully understood. 

As the substance became less substantial, the nature of space and time also became more diffused inside the atom. This phenomenon of quantization was simply bypassed when material units of space and time were used. This amounted to treating space and time as absolute.

I am, however, going to transgress to the extent of writing down one mathematical formula for you to contemplate; I shall not be so unreasonable as to expect you to understand it. All authorities seem to be agreed that at, or nearly at, the root of everything in the physical world lies the mystic formula

qp—pq = ih/2π

We do not yet understand that; probably if we could understand it we should not think it so fundamental. Where the trained mathematician has the advantage is that he can use it, and in the past year or two it has been used in physics with very great advantage indeed. It leads not only to those phenomena described by the older quantum laws such as the h rule, but to many related phenomena which the older formulation could not treat.

On the right-hand side, besides h (the atom of action) and the merely numerical factor 2π, there appears i (the square root of -1) which may seem rather mystical. But this is only a well-known subterfuge; and far back in the last century physicists and engineers were well aware that √-1i in their formulae was a kind of signal to look out for waves or oscillations. The right-hand side contains nothing unusual, but the left-hand side baffles imagination. We call q and p co-ordinates and momenta, borrowing our vocabulary from the world of space and time and other coarse-grained experience; but that gives no real light on their nature, nor does it explain why qp is so ill-behaved as to be unequal to pq.

It is here that the three theories differ most essentially. Obviously q and p cannot represent simple numerical measures, for then qp—pq would be zero. For Schrodinger p is an operator. His “momentum” is not a quantity but a signal to us to perform a certain mathematical operation on any quantities which may follow. For Born and Jordan p is a matrix—not one quantity, nor several quantities, but an infinite number of quantities arranged in systematic array. For Dirac p is a symbol without any kind of numerical interpretation; he calls it a q-number, which is a way of saying that it is not a number at all.

I venture to think that there is an idea implied in Dirac’s treatment which may have great philosophical significance, independently of any question of success in this particular application. The idea is that in digging deeper and deeper into that which lies at the base of physical phenomena we must be prepared to come to entities which, like many things in our conscious experience, are not measurable by numbers in any way; and further it suggests how exact science, that is to say the science of phenomena correlated to measure-numbers, can be founded on such a basis.

One of the greatest changes in physics between the nineteenth century and the present day has been the change in our ideal of scientific explanation. It was the boast of the Victorian physicist that he would not claim to understand a thing until he could make a model of it; and by a model he meant something constructed of levers, geared wheels, squirts, or other appliances familiar to an engineer. Nature in building the universe was supposed to be dependent on just the same kind of resources as any human mechanic; and when the physicist sought an explanation of phenomena his ear was straining to catch the hum of machinery. The man who could make gravitation out of cog-wheels would have been a hero in the Victorian age.

Nowadays we do not encourage the engineer to build the world for us out of his material, but we turn to the mathematician to build it out of his material. Doubtless the mathematician is a loftier being than the engineer, but perhaps even he ought not to be entrusted with the Creation unreservedly. We are dealing in physics with a symbolic world, and we can scarcely avoid employing the mathematician who is the professional wielder of symbols; but he must rise to the full opportunities of the responsible task entrusted to him and not indulge too freely his own bias for symbols with an arithmetical interpretation. If we are to discern controlling laws of Nature not dictated by the mind it would seem necessary to escape as far as possible from the cut-and-dried framework into which the mind is so ready to force everything that it experiences.

I think that in principle Dirac’s method asserts this kind of emancipation. He starts with basal entities inexpressible by numbers or number-systems and his basal laws are symbolic expressions unconnected with arithmetical operations. The fascinating point is that as the development proceeds actual numbers are exuded from the symbols. Thus although p and q individually have no arithmetical interpretation, the combination qp—pq has the arithmetical interpretation expressed by the formula above quoted. By furnishing numbers, though itself non-numerical, such a theory can well be the basis for the measure-numbers studied in exact science. The measure-numbers, which are all that we glean from a physical survey of the world, cannot be the whole world; they may not even be so much of it as to constitute a self-governing unit. This seems the natural interpretation of Dirac’s procedure in seeking the governing laws of exact science in a non-arithmetical calculus.

I am afraid it is a long shot to predict anything like this emerging from Dirac’s beginning; and for the moment Schrodinger has rent much of the mystery from the p’s and q’s by showing that a less transcendental interpretation is adequate for present applications. But I like to think that we may have not yet heard the last of the idea.

Schrodinger’s theory is now enjoying the full tide of popularity, partly because of intrinsic merit, but also, I suspect, partly because it is the only one of the three that is simple enough to be misunderstood. Rather against my better judgment I will try to give a rough impression of the theory. It would probably be wiser to nail up over the door of the new quantum theory a notice, “Structural alterations in progress—No admittance except on business”, and particularly to warn the doorkeeper to keep out prying philosophers. I will, however, content myself with the protest that, whilst Schrodinger’s theory is guiding us to sound and rapid progress in many of the mathematical problems confronting us and is indispensable in its practical utility, I do not see the least likelihood that his ideas will survive long in their present form.

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Eddington 1927: Transition to a New Theory

Geometry of space

Reference: The Nature of the Physical World

This paper presents Chapter X (section 2) from the book THE NATURE OF THE PHYSICAL WORLD by A. S. EDDINGTON. The contents of this book are based on the lectures that Eddington delivered at the University of Edinburgh in January to March 1927.

The paragraphs of original material are accompanied by brief comments in color, based on the present understanding.  Feedback on these comments is appreciated.

The heading below links to the original materials.

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Transition to a New Theory

By 1925 the machinery of current theory had developed another flaw and was urgently calling for reconstruction; Bohr’s model of the atom had quite definitely broken down. This is the model, now very familiar, which pictures the atom as a kind of solar system with a central positively charged nucleus and a number of electrons describing orbits about it like planets, the important feature being that the possible orbits are limited by the rules referred to on p. 190. Since each line in the spectrum of the atom is emitted by the jump of an electron between two particular orbits, the classification of the spectral lines must run parallel with the classification of the orbits by their quantum numbers in the model. When the spectroscopists started to unravel the various series of lines in the spectra they found it possible to assign an orbit jump for every line—they could say what each line meant in terms of the model. But now questions of finer detail have arisen for which this correspondence ceases to hold. One must not expect too much from a model, and it would have been no surprise if the model had failed to exhibit minor phenomena or if its accuracy had proved imperfect. But the kind of trouble now arising was that only two orbit jumps were provided in the model to represent three obviously associated spectral lines; and so on. The model which had been so helpful in the interpretation of spectra up to a point, suddenly became altogether misleading; and spectroscopists were forced to turn away from the model and complete their classification of lines in a way which ignored it. They continued to speak of orbits and orbit jumps but there was no longer a complete one-to- one correspondence with the orbits shown in the model.*

*Each orbit or state of the atom requires three (or, for later refinements, four) quantum numbers to define it. The first two quantum numbers are correctly represented in the Bohr model ; but the third number which discriminates the different lines forming a doublet or multiplet spectrum is represented wrongly—a much more serious failure than if it were not represented at all.

Bohr’s model of atom is inconsistent with the atomic spectra. The classification of the orbits by their quantum numbers in the model ceases to explain the finer details of the spectral lines.

There are neither electrons nor any orbits within the atom. There is only rotating field-substance with its various quantization levels. There are field particles as a result of quantization. The spectral lines relate to the absorption and emission of these field-particles.

The time was evidently ripe for the birth of a new theory. The situation then prevailing may be summarised as follows:

(1) The general working rule was to employ the classical laws with the supplementary proviso that whenever anything of the nature of action appears it must be made equal to h, or sometimes to an integral multiple of h.

(2) The proviso often led to a self-contradictory use of the classical theory. Thus in the Bohr atom the acceleration of the electron in its orbit would be governed by classical electrodynamics whilst its radiation would be governed by the h rule. But in classical electrodynamics the acceleration and the radiation are indissolubly connected.

(3) The proper sphere of classical laws was known. They are a form taken by the more general laws in a limiting case, viz. when the number of quanta concerned is very large. Progress in the investigation of the complete system of more general laws must not be hampered by classical conceptions which contemplate only the limiting case.

(4) The present compromise involved the recognition that light has both corpuscular and wave properties. The same idea seems to have been successfully extended to matter and confirmed by experiment. But this success only renders the more urgent some less contradictory way of conceiving these properties.

(5) Although the above working rule had generally been successful in its predictions, it was found to give a distribution of electron orbits in the atom differing in some essential respects from that deduced spectroscopically. Thus a reconstruction was required not only to remove logical objections but to meet the urgent demands of practical physics.

Electrons do not exist as such within the atom. They are only formed out of atomic reactions. The structure of atom is explained by certain quantum numbers. These quantum numbers needs to be explained in terms of quantization of field-substance.

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